Plating metal with copper at home. Electrotype
Copper plating is the process of applying a copper layer to the surface using an electroplating method.
The copper layer gives the product visual appeal, which allows the use of copper electroplating in design projects. It also gives the metal high electrical conductivity, which allows the product to be subjected to further surface treatment.
Copper plating can be used as the main process to create a surface layer, and also as an intermediate operation for the subsequent application of another metal layer. This method includes, for example, the process of silvering, chrome plating or nickel plating.
Copper plating can be done at home. This makes it possible to solve many everyday problems.
Electroplating at home: equipment and materials
To perform copper coating yourself, you need to purchase the necessary equipment and materials for the process.
First of all, you need to prepare a source of electric current. Various home craftsmen advise using current strength, which varies over a wide range. Work must be carried out on direct current.
As a current source, you can take a KBS-L battery with a voltage of 4.5 volts or a new Krona brand battery with an operating voltage of 9 volts. You can also use a low-power rectifier instead, which produces a voltage of no more than 12 volts, or a car battery.
It is mandatory to use a rheostat to regulate the voltage and smooth exit from the process.
For the electrolyte solution, a neutral container should be prepared, for example, made of glass, as well as wide plastic dishes that are sufficiently sized to accommodate the part. Containers must withstand temperatures of at least 80°C.
You will also need anodes to ensure coverage of the entire surface of the part. They are designed to supply current to the electrolyte solution and distribute it over the entire area of the part.
To carry out electroplating at home, you will also need chemicals to prepare the solution:
- copper sulfate,
- hydrochloric or other acid,
- distilled water.
Having prepared everything you need, you can start working.
Copper plating of steel products
Copper plating of steel with copper sulfate is one of the main processes in the field of electroplating because it is used to pre-plate copper. It has high adhesion to the steel surface, unlike other metals that do not have good adhesion to steel. If the technology is followed, the copper layer adheres perfectly to steel products.
There are two coating technologies: with immersing the product in an electrolyte solution and a method of non-contact coating of the surface with copper without placing it in a liquid electrolyte solution.
Copper plating by immersion
The process is carried out following the following steps:
- The oxide film is removed from the surface of the steel part using sandpaper and a brush, and then the part is washed and degreased with soda and a final rinse with water.
- Two copper plates are placed in a glass jar, connected to copper conductors, which serve as the anode. To do this, they are connected together and connected to the positive terminal of the device used as a current source.
- The workpiece is suspended freely between the plates. The negative pole of the terminal is connected to it.
- A tester with a rheostat is built into the circuit to regulate the current.
- An electrolyte solution is prepared, which usually includes copper sulfate - 20 grams, acid (hydrochloric or sulfuric) - from 2 to 3 ml, dissolved in 100 ml (preferably distilled) water.
- The prepared solution is poured into a prepared glass jar. It should completely cover the electrodes placed in the jar.
- The electrodes are connected to a current source. Using a rheostat, the current is set (10-15 mA should be per 1 cm2 of part area).
- After 20-30 minutes, the current is turned off, and the copper-plated part is removed from the container.
Copper plating without immersion in electrolyte solution
This method is used not only for steel products, but also for aluminum and zinc products. The process goes like this:
- A stranded copper wire is taken, the insulating coating is removed from one end, and the copper wires are given the appearance of a kind of brush. For convenient use, the “brush” is attached to a handle-holder (you can take a wooden stick).
- The other end of the wire without a brush is connected to the positive terminal of the voltage source being used.
- An electrolyte solution is prepared based on concentrated copper sulfate with the addition of a small amount of acid. It is poured into a wide container, necessary for convenient dipping of the brush.
- The prepared metal part, cleaned of the oxide film and degreased, is placed in an empty bath and connected to the negative terminal.
- The brush is moistened with the prepared solution and moved along the surface of the plate without touching it.
- Once the required copper layer has been achieved, the process ends and the part is washed and dried.
There should always be a layer of electrolyte solution between the surface of the part and the improvised copper brush, so the brush must be dipped in the electrolyte constantly.
Copper plating of aluminum with copper sulfate
Copper coating is a great way to update aluminum cutlery and other aluminum products used in the home.
Copper plating of aluminum with copper sulfate can be done independently. A simplified option to demonstrate the process is to coat a simple shaped aluminum plate with copper.
You can practice with this example. The process goes like this:
1. The surface of the record must first be cleaned and then degreased.
2. Then you need to apply a little concentrated solution of copper sulfate (copper sulfate) to it.
3. The next step is to connect the wire connected to the negative pole to the aluminum plate. You can connect the wire to the plate using a regular clamp.
4. A positive charge is applied to a device consisting of bare copper wire with a diameter of 1 to 1.5 mm, the end of which is distributed between the bristles of the toothbrush.
During operation, this end of the wire should not touch the surface of the aluminum plate.
5. Having dipped the bristles in a solution of copper sulfate, begin to move the brush in the place prepared for coating with copper. In this case, there is no need to close the circuit by touching the surface of the aluminum plate with the end of the copper wire.
6. Copper plating of the surface immediately becomes visually noticeable. In order for the layer to be of high quality, there is no need to rush to complete the process.
7. After completing the work, the copper layer must be leveled by additional cleaning, removing the remaining copper sulfate and wiping the surface with alcohol.
Galvanoplasty at home
Galvanoplasty is the process of electrochemical action on a product in order to give it the required shape by depositing metal on the surface.
Typically this technology is used for metal coating of non-metallic products. It is widely used in jewelry and the design of household items.
The coating of the work product must have electrically conductive properties. In the absence of such a layer, the object is first coated with graphite or bronze.
The main metals used for electroforming are copper, nickel, silver and chromium. Metallization of surfaces with steel alloys is also used.
Electroplating at home is especially popular among craftsmen. To create the desired shape, a cast is made from the copy. For this purpose, easily melting metal, graphite and gypsum are used.
After the mold is made, the object is plated using an electrolyte.
(2 5,00 out of 5)
Source: https://plavitmetall.ru/obrabotka/mednenie-v-domashnix-usloviyax.html
Galvanic copper plating
Modern technology puts forward strict requirements for the characteristics of structural elements; in many cases, these problems are solved by chemical copper plating. The use of special coatings for the surfaces of parts is economically beneficial, since galvanic copper plating makes it possible to reduce the metal consumption of products made from expensive metals.
Physical and mechanical characteristics of copper and areas of use of copper plating
Copper density 8.96 g/cm3, atomic mass 693.54, electrical resistivity 1.68×10-8 Ohm×m, melting point +1083°C. In the open air, in the presence of aggressive chemical compounds, copper oxidizes, and upon contact with sulfur compounds, it becomes covered with a film of copper sulfide of dark brown or gray shades.
Under the influence of carbon dioxide and moisture, the film becomes green; the top layer consists of hydrocarbonates. Copper easily dissolves in a solution of nitric acid; diluted sulfuric acid has almost no negative effect on chemical copper plating. But the presence of oxygen increases the rate of chemical reactions. If there are open pores in the coating, a galvanic couple is formed, which must be taken into account when plating copper.
In this case, iron is the anode, and corrosion processes occur very intensively.
Due to such features, the copper plating process in most cases must be completed with additional surface treatment. Coatings are sanded or polished to a mirror finish. Copper has high adhesion to various metals: aluminum, silver, zinc, nickel, lead, chromium, etc.
Due to these features, chemical copper plating is often used to create a sublayer when plating silver, nickel, or chrome plating the surfaces of parts. Copper plating has become widespread as a method of effectively protecting individual parts of parts from the appearance of the carburizing effect during the carburizing process.
Depending on the purpose of parts or products, electroplated copper can have the following thickness:
Thickness of the copper layer on the surface of the workpieces
Comparative indicators of solutions
In the copper plating process, a large number of special technological solutions are used, divided into two large groups:
- A simple acidic electrolyte. Of the simple ones, fluoroborate, silicofluoride, sulfate, chloride and sulfamide solutions are used.
- Complex electrolyte. Primarily alkaline, copper is present as positively or negatively charged complex ions.
Graph of polarization curves of copper deposition from various types of electrolytes
The deposition process in acidic electrolytes occurs at high current densities; they are stable and simple in chemical composition. The main components are the corresponding acids and salts; the copper deposits from them are quite dense and have a coarse-crystalline structure. Disadvantages - direct copper plating of steel, zinc alloys and other metals occurs with a lower negative potential than copper.
Processing of parts in complex electrolytes is carried out using complex ions; they require high cathodic polarization. The current output is lower, which contributes to more uniform deposition; the structure is fine-crystalline. Pyrophosphate, cyanide, ammonium, tripolyphosphate, citrate and other solutions are used.
Electrolyte Dissipation Capacity for Copper Plating
Simple acidic compounds
- Sulfate. The main components are sulfuric acid and copper sulfate. The sulfuric acid compound has low electrical conductivity; sulfuric acid is added to increase the parameter. The current efficiency of copper reaches 100%, and no hydrogen is released at the cathode. By increasing the acid concentration, the solubility of the sulfate decreases, which lowers the upper limit of the maximum permissible current density.
Effect of sulfuric acid content on the electrical conductivity of the electrolyte
When stirring, the concentration of copper ions on the cathode layer increases. As the temperature rises, the solubility of copper sulfate increases, the electrolyte increases acidity, which leads to the formation of fine-crystalline precipitates.
To improve cathodic polarization, surfactants are added to the electrolyte. Additionally, they reduce the formation of build-up on sharp edges.
Modes and composition of sulfate electrolytes for copper plating
To form a shiny coating, AMF anodes are used, which do not allow the formation of sludge, or anodes made of especially pure refined copper.
Effect of copper concentration on current density with stirring (1) and without stirring (2). Fluoroborate electrolyte.
Fluoroborate electrolyte.
To prevent the ingress of sludge, the anodes are placed in covers made of acid-resistant material; in addition, the solution is constantly filtered.
- Fluoroborate. They are highly resistant, the electroplating is dense and fine-crystalline, and the dissipation properties are the same as with copper sulfate plating. Due to the high solubility, the current density increases; it is impossible to deposit copper directly on the part.
Composition and operating mode of fluoroborate electrolytes
With continuous stirring, it is allowed to increase the current density. Control of technological parameters of copper plating is carried out by measuring the acidity of the solution. To improve the quality of copper plating, sodium carbonate is used, and copper sulfate is used to reduce it.
- Nitrate. The electrolyte is used in electroplating and provides improved quality of the deposit.
Regimes and composition of nitrate electrolytes
Complex electrolytes
- Cyanide. The processing conditions differ significantly from acid precipitation; in them, copper exists in the form of complex ions, which significantly reduces its activity. An increase in current density forces the cathode potential to sharply shift into a field of negative values. But the copper plating process cannot be carried out at increased current density due to the fact that the copper yield may drop to zero. The main components of the solution are free sodium cyanide and complex potassium cyanide. During operation, the copper content decreases due to their insufficient solubility.
Mode and composition of cyanide electrolytes for copper plating
- Pyrophosphate. Copper deposits have a fine-crystalline structure, smooth, shiny or semi-shiny. To improve the quality of processing and increase the cathode and anodic densities, copper sulfate can be added. The cathodic potential in pyrophosphate solutions has more negative parameters than in acid solutions.
Mode and composition of pyrophosphate electrolytes
- Ethylenediamine. The copper plating process can be carried out directly on the surface of the steel; at low current densities, cathodic polarization reaches high values. The scattering characteristics are higher than those of sulfate solutions, but lower than those of a cyanide solution.
Mode and composition of ethylenediamine electrolytes
and unloading of parts must be carried out at a minimum current strength; in the first 40–50 seconds, a current impulse is given, three times higher than the operating values of copper plating.
- Polyethylenepolyamine. During the processing of parts, the potentials shift to a field of negative values, and an electrolyte is used instead of cyanide.
Operating mode and compositions of polyethylene-polyamine electrolytes
- Ammonium. The composition includes ammonia, ammonium sulfate and copper sulfate. At low current densities, the current efficiency decreases; copper plating is improved by adding ammonium nitrate. The sediments are uniform in thickness, dense and semi-shiny.
Operating modes and composition of ammonium electrolyte
Without special surface treatment, copper deposits have insufficient adhesion, the reason is the passivation of steel with an ammonia solution.
Improvement of coating parameters is achieved by introducing copper nitrate into the solution. Design of a copper plating bathLinear parameters and design features must meet the requirements of GOST 23738-85. The galvanic bath is made of modified, highly resistant plastics; specific grades are selected taking into account the parameters of technological processes.
Bath without a pocket. The simplest design, used both individually and on production lines.
Bath without pocket
Bathtub with pocket. Treatment can be carried out with simultaneous processes of removing the upper contaminated electrolyte layer.
Bathtub with pocket
The specific choice of a copper plating bath is made depending on the characteristics of the enterprise, the characteristics of the parts to be copper plated and the overall production capacity.
During design, the maximum loads are calculated taking into account the volume of the solution; the length, height and width can be changed at the request of customers. If necessary, additional equipment and water fittings are installed on copper plating baths. Due to special mechanisms, the quality of the copper plating process is improved. The plastics used are adapted to the chemical composition of the electrolyte and the temperature conditions of copper plating.
Mechanical surface preparation
Before copper plating, scale, burrs and shells must be removed from the surface. The quality of processing is regulated by the provisions of the current GOST 9.301-86. Specific roughness parameters are set depending on the purpose of the coating.
After machining the parts, all defects that have a negative impact on the quality of copper plating must be removed from the surface.
Technical grease and emulsion, metal shavings, products of corrosion processes and dust must be removed.
Preparation for copper plating is carried out during the following technological operations:
- Grinding. The top layer of parts is removed with abrasive elements; it can be thin, decorative or rough.
- Polishing. During the operation, the smallest protrusions are smoothed out, the surface is shiny and mirror-like.
- Brushing. Metal brushes are used to clean surfaces.
- Tumbling. The parts are rolled in special bells.
- Chemical and electrochemical degreasing. Organic and inorganic solutions are used for processing.
The copper plating process and physical indicators of precipitation largely depend on the quality of preliminary surface preparation.
Source: https://plast-product.ru/galvanicheskoe-mednenie/
How to coat steel with copper at home - Metalworker's Guide
The process of copper plating of metal products is called electroplating. It is based on the deposition of another metal, soluble in a special liquid, onto the surface of parts.
Copper plating technology includes the production of a solution and the creation of dissimilar electrodes. During the electroplating process, copper ions dissolved in the electrolyte are attracted by the negative pole (workpiece) to its surface.
Copper plating of various parts on an industrial scale is used not only as a final process for treating the surface of metal products. It can be used to prepare parts for the next operation, for example, nickel, silver or chrome plating of products.
These metals do not deposit well on the surface of steel parts, but they adhere very well to copper-plated surfaces. In turn, copper deposited on steel parts holds firmly and helps smooth out various defects on its surface.
Copper plating of parts in a solution with electrolyte
For metal parts, you can perform copper plating at home. Let's consider copper plating, with the part being lowered into a solution with an electrolyte. To do this you need to have:
- small copper plates,
- several meters of conductive wire;
- current source, with voltage up to 6 V;
- It is also recommended to use a rheostat to regulate the current and an ammeter.
Operating procedure
- An ordinary electrolyte is used as a liquid that dissolves copper well. You can buy it or prepare it at home. This will require 3 ml of sulfuric acid for every 100 ml of distilled water . The required solution can be obtained by adding up to 20 g to the resulting electrolyte. copper sulfate.
- Before starting the copper plating process, the part must be cleaned with sandpaper to remove the oxide film from the surface.
- Then, the part is degreased with a hot soda solution and washed with clean water.
- The prepared electrolyte solution is poured into a glass container of the required volume.
- Then, two copper plates are lowered there, on current-carrying wires. Between two copper plates, a part intended for copper plating at home is suspended on a similar wire. It is necessary to ensure that the copper plates and the part are completely filled with the electrolyte solution.
- At the next stage, the ends of the wires from the copper plates are connected to the positive terminal, and the workpiece to the negative terminal of the current source. A rheostat and an ammeter must be connected in series to the created electrical circuit. After turning on the current in the circuit, it is set by a rheostat within 15 mA per 1 cm? surface area of the part.
- After keeping the workpiece in the solution for 15-20 minutes, you need to turn off the power supply and remove the product from the solution. During this short period of time, the surface of the part will be covered with a thin layer of copper. The thickness of the coating will depend on the duration of the copper plating process. Thus, it is possible to achieve copper plating of the surface of any product with a layer of 300 microns or more.
Copper plating of the part, without immersion in the solution
The second method of copper plating metal products at home involves performing this process without immersing the workpiece in an electrolyte solution.
This option is suitable for coating zinc and aluminum products.
Operating procedure
- For this method of copper plating, you will need a stranded copper wire, from both ends of which it is necessary to remove the insulation. On one side, the soft wire needs to be ruffled. This produces a product in the form of a brush. To make it more convenient to work in the future, you need to tie a solid object in the form of a handle to this end of the wire. The second cleaned end of the wire must be connected to the positive terminal of the electric current source. The voltage should not exceed 6 V.
- Using the previously described method, you need to prepare an electrolyte mixed with copper sulfate. In this method of copper plating of parts, the solution can be poured into any container. It is recommended to choose a wide container so that it is convenient to dip the copper wire brush. Next, you need to place a small metal piece in this dish, with low edges. First you need to clean it, boil it in liquid with washing powder, and rinse it. This part must be connected using a wire to the negative terminal of the current source, with a voltage of 6 V.
- The copper plating process occurs as follows. The frayed end of the copper wire must be periodically dipped in an electrolyte solution with copper sulfate and passed along the part without touching its surface with a “brush”. But it is necessary to ensure that there is a small layer of solution between the end of the brush and the part (the cathode and anode must always be moistened with electrolyte). During the copper plating process, the negatively charged part attracts copper ions and its surface is covered with a small red layer. After applying the coating, the product must be dried and rubbed until shiny.
This type of copper plating, without immersing the product in an electrolyte, is often used to process large parts. They do not fit into the selected container with electrolyte, and the surface is treated with a brush in small areas.
guide to copper plating at home
2016-01-11
Source: https://ssk2121.com/kak-pokryt-medyu-stal-v-domashnih-usloviyah/
How to coat steel with copper at home?
In order to prepare a metal object for further processing, it must be coated with copper - this process is called electroplating. The principle of its operation is to deposit onto the surface of the workpiece from another metal, which is dissolved with a suitable means. From this article you will learn how to coat metal with copper at home in order to realize all your subsequent ideas with the workpiece.
What is it for?
Electroplating technology involves creating a solution and forming various electrodes. During this process, copper ions, which are dissolved in the electrolyte, are attracted by the negative pole of the workpiece to their surface point.
Electroplating of metal parts in industry is used not only as a final processing process. It can be used to prepare parts for subsequent operations (for example, chrome plating, nickel plating, silver plating of any objects).
Chemical copper plating of parts is most often carried out at home. It is also worth noting that there are many ways to carry out such a procedure, each of which has its own advantages and disadvantages.
Areas of use of galvanostegy
Coating metal with copper at home has recently become very useful. Most often, this procedure is approached for the following purposes:
- In decorative. For example, various parts are aged in this way in order to give a vintage look.
- In galvanoplasty. Very often a copper layer is applied to souvenirs and jewelry.
- In the technology industry. This is due to the low cost of copper plating.
- For applying a protective and decorative layer of a particular product.
- In order to restore or restore any parts.
Electroplating with electrolyte solution
In this way, you can coat steel with copper at home, as well as other parts except aluminum and zinc.
For the further procedure, it is necessary to prepare the following materials:
- Small plates of copper.
- Conductive wire (it’s better to stock up on a few meters).
Source: https://varimtutru.com/kak-pokryt-medyu-stal-v-domashnih-usloviyah/
How to coat steel with copper at home
Surface treatment of various objects is carried out to give a decorative effect or as an intermediate procedure preceding further actions. Many processes are easy to implement and do not require much equipment. One of the most popular processing methods is copper plating, which can also be done at home.
What is the copper plating process?
Copper plating is the process of applying a thin layer of copper to the surface of an object. It is performed by the galvanic method, that is, by transferring copper ions from a positively charged source to a negatively charged surface to be treated.
Most often, the process of electroplating copper is a preparatory step before plating with nickel and chromium, but often copper plating of metal becomes an independent type of finishing.
Electroplating, which requires the creation of a copper coating, is widely used.
Types of copper plating
There are two options for copper plating at home:
- With immersion of the workpiece in electrolyte.
- No immersion.
With immersion of the workpiece in electrolyte. To perform the procedure, you must have a container with electrolyte of sufficient volume. After preliminary preparation, which consists of cleaning the surface with sandpaper and rinsing it in a hot soda solution, the object is connected to the negative electrode and immersed in the electrolyte for a certain time.
Copper plating with immersion of the part in electrolyte
No immersion. Can process steel, aluminum, lead, zinc. Processing is carried out without immersion in a container; this option is usually used for large parts.
Both options are quite accessible for doing it yourself at home.
Equipment and materials required for copper plating
To carry out copper plating of steel or other metals, you will have to stock up on some materials and devices. You will need:
- Hydrochloric acid.
- Copper sulfate (copper sulfate).
- Distilled water.
Source: https://steelfactoryrus.com/kak-pokryt-medyu-stal-v-domashnih-usloviyah/
Copper plating of steel at home - Metals, equipment, instructions
When it comes to electroplating, technological operations such as chrome plating and galvanizing of metal products immediately come to mind. But if you ask the question, what is galvanostegy, not everyone will answer - it has been verified. Although this term does not imply anything supernova.
Simply put, this is a technique for coating any material with a thin layer of metal, be it steel, aluminum, wood or plastic. We’ll figure out how to copper-plate a sample at home.
general information
Copper plating is a technique that is somewhat more universal than galvanizing. For what purposes is it carried out?
- Protection of samples from carburization before cutting them, as well as from corrosion.
- Elimination of defects on the surfaces of parts when other methods are unacceptable or difficult to implement. For example, if the base is characterized by complex terrain.
- Decoration of products.
- Creating copies of samples from other materials.
- Preparation of steel parts for chrome plating, silver plating, and gold plating. In such cases, copper plating is only one of the stages of surface treatment of the material.
- To create solderable segments.
It is unlikely that the reader will be interested in such nuances as the classification of copper (refined, oxygen-free, general use), various options for solutions used in copper plating, characteristics of materials and similar things. Below we consider only the simplest methods of applying Cu to any surface, which are easy to organize at home, without any difficulties or financial costs.
Copper plating in electrolyte
This technique is only suitable for coating metal parts with a layer of Cu. In fact, the technology is not much different from galvanizing at home.
Preparation
The equipment you will need is simple:
Glass bath (container). Its capacity is determined by the dimensions of the workpiece. Even a liter jar or glass are options.
Copper electrodes. Typically, two are used. This allows you to better coat the workpiece with a layer on all sides and simplifies the process itself. As you work, you will not have to periodically change the position of the part relative to the electrode. What exactly to use depends on the specific situation - copper plates, pieces of thick wire. This is unprincipled.
Source: https://spb-metalloobrabotka.com/mednenie-stali-v-domashnih-usloviyah/
How to coat metal with copper at home?
In order to prepare a metal object for further processing, it must be coated with copper - this process is called electroplating. The principle of its operation is to deposit onto the surface of the workpiece from another metal, which is dissolved with a suitable means. From this article you will learn how to coat metal with copper at home in order to realize all your subsequent ideas with the workpiece.
Copper plating technology and its use at home
Copper is one of the most widely used metals in the world; this material has long been used to make tools. This active use of copper is due to its unique technical and operational properties.
Currently, without copper it is impossible to exist in such industries as metallurgy, the automotive industry, electrical engineering and construction.
This material is also necessary at home, which is why many are so interested in how to carry out copper plating at home.
What is copper plating?
Copper plating is usually understood as the electroplating of copper, and the layer thickness should range from one to three hundred micrometers. Copper plating is the coating of copper on a metal product in preparation for chrome plating, nickel or silver plating. However, this procedure can also be used as an independent surface treatment.
As a preparatory process, copper plating of steel helps to level the surface, because, as you know, copper adheres firmly to steel, which cannot be said about other materials. Various metals are deposited quite well on a copper-plated coating (much better than on pure steel).
Experts include high adhesion to other metals, ductility and reliability among the distinctive characteristics of copper coating. However, with constant exposure to environmental factors, the copper coating quickly oxidizes and becomes covered with rainbow stains, spots and plaque.
Copper plating can be done on surfaces made of steel, zinc and even aluminum. The newly applied copper layer has a crimson tint with a slightly noticeable metallic sheen.
Where is it used?
There are several main cases of using copper plating:
- For decoration. Recently, the demand for antique copper products has increased. Using a special treatment, the applied layer of copper gives the surface an “aged look”.
- Galvanic copper plating. This method of applying iron is used to produce copies of individual copper parts of various shapes and sizes. First, a base of wax or plastic is created, which is subsequently coated with an electrically conductive solution and a copper layer. This technology is widely used in the manufacture of souvenirs, jewelry, as well as bas-reliefs and waveguides.
- In electrical engineering. The low cost of copper plating makes this method stand out - in comparison with coatings made of silver or gold, copper products can be used in the electrical industries (for the production of electrodes, live contacts and as a base for soldering).
Copper plating technology is also combined with various types of galvanization:
- To create a multi-layer decorative coating with weak protective characteristics. In this case, copper, chromium and nickel are used - a three-layer protective and decorative layer, which increases the degree of adhesion to the main surface material.
- To protect a specific area of a part during carburizing. When galvanizing lead products with copper, it is necessary to protect the coatings of steel elements from carburization. Only those areas that will be subsequently subjected to mechanical processing can be copper plating.
- During restoration work. During the copper plating process, an intermediate layer is formed on the restored part, which will subsequently serve as the basis for a more durable coating (chrome plating, nickel plating). The galvanic method is characterized by the application of a thick layer of copper, up to two hundred and fifty micrometers. This is due to the need to eliminate all damage and surface defects.
Source: https://GidPoKraske.ru/spetsialnye-materialy/obrabotka-metallicheskih-predmetov/mednenie-v-domashnih-usloviyah.html
Copper plating of aluminum at home: types and technologies
Copper plating is the process of applying a layer of copper to the surface of various metals (aluminum, steel, nickel, brass). Copper plating gives metals a visual appeal that can be used in a variety of design projects. Also, the copper layer can improve the electrical conductivity of metal products, which significantly increases the possibility of further surface treatment.
Anyone who is at least a little familiar with the basics of chemical reactions can master the technology of copper plating aluminum at home.
History of the discovery of copper
Copper is the first metal that was conquered by man and played the greatest significance in the history of the development of civilization. This event took place several thousand years BC, and the exact date of the beginning of the use of this unique metal could not be established.
In ancient times, copper nuggets were used mainly to create weapons and household tools. Red-green metal nuggets were initially used in the same way as ordinary stones. Later, through experience, people noticed that processing this material with a hammer gives it special properties. This is how cold metal forging was born.
Even later, it was discovered that the metal melts and, after cooling, takes on different shapes and properties. This stage was the initial stage in the development of hot metal forming.
Characteristics and composition of copper
Copper is a heavy metal with a rose-red color, which is highly soft and melts at a temperature of more than 1080℃. The electrical conductivity of copper coating is 1.7 times higher than that of aluminum. Copper also has high thermal conductivity.
Many specific properties of the metal are due to the presence of various impurities in its composition. So, according to the oxygen that copper contains, the metal is divided as follows:
- copper without oxygen contains impurities of less than 0.001%;
- refined copper contains oxygen 0.001–0.01%;
- pure copper contains oxygen about 0.03–0.05%;
- General purpose copper contains 0.05–0.08% oxygen.
The presence of lead or bismuth in copper reduces the plasticity properties of the material. Slightly soluble impurities (sulfur, lead, bismuth) increase the fragility of the metal.
During the electrolysis process, in addition to oxygen, hydrogen can enter the composition of copper alloys.
Physical properties
The main quality of copper is low resistivity and, as a result, high electrical conductivity. An increase in impurities of various metals in a copper alloy significantly reduces the electrical conductivity of the material.
The high thermal conductivity of pure copper is significantly reduced when various alloying substances are added to its composition.
Also often used in industry are copper products that are highly resistant to corrosion in various environments, except organic acids, ammonia and ammonium salts. An increase in the amount of impurities in the copper composition leads to a significant decrease in the corrosion resistance of the alloys.
Practical application of copper plating of metals
The procedure for copper plating of aluminum and other metals has a fairly wide practical application not only in domestic use, but also on an industrial scale. On many metals, a copper coating can be applied both as a main independent layer and as a sublayer for effective adhesion of the next main coating to the base metal of the product.
In most cases, copper plating of aluminum in home workshops is carried out for the following purposes:
- decoration of jewelry;
- protection of metal parts from corrosion and cementation;
- elimination of damage and surface defects of products with complex shapes and reliefs;
- making copies of products made from various materials;
- creating contact pads for soldering aluminum without the use of an acid composition;
- preliminary preparation of the surface of parts before chrome, silver, and nickel plating.
Types of copper plating of a metal surface
The procedure for copper plating aluminum at home is not difficult to do yourself. It is not necessary to use special equipment and active chemicals. High-quality coating is ensured through strict adherence to aluminum copper plating technology and knowledge of the ongoing processes.
There are two main types of copper plating of metal surfaces:
- With the immersion of a workpiece in an electrolyte, in which the product is partially or completely immersed in a bath of a chemical reagent. The use of this method is justified when it is necessary to apply a layer of copper evenly over the entire product.
- Copper plating without immersing the part in a chemical solution. This method is more difficult to implement. Its use is very effective if you need to copper plating a certain area of the product.
In both of these cases, the activation of the substance for chemical copper plating of aluminum is carried out electrically, which requires the use of a constant voltage source.
Immersion Copper Plating Equipment
To perform high-quality technological operations of aluminum copper plating, it is necessary to prepare simple equipment. The corresponding tools and materials can either be purchased at a retail chain or made independently.
To complete the work you will need the following materials and equipment:
- A 6-8 volt DC power supply with a continuously variable current control device and an ammeter. If there is no adjustment, then it is advisable to include a rheostat and an ammeter in the circuit. They will be needed to control the process. If there is no stationary power supply, then you can use a Krona type battery.
- A special bath made of material that is not subject to electrolytic effects (glass, plastic). The dimensions of the container are selected in accordance with the dimensions of the workpiece.
- Copper electrodes, which serve to supply electric current to the electrolyte during copper plating of aluminum, and also replenish the loss of metal during the reaction.
- Electrolyte, the composition of which depends on the material of the original workpiece.
Preparation of solution for copper plating
It is difficult to find a ready-made solution for copper plating of aluminum in the retail chain. Typically, manufacturers allow the sale of the finished substance upon presentation of the appropriate documents. Therefore, most people make their own solution for copper plating of aluminum at home from copper sulfate.
For these purposes you will need:
- copper sulfate;
- distilled water;
- hydrochloric acid.
The solution can only be prepared if the recipe is followed correctly. To do this, you need to dissolve copper sulfate (20 g) in 1 liter of water. Then add 2-3 ml of acid in a thin stream. The composition is thoroughly mixed until all crystals are completely dissolved.
The finished electrolyte for copper plating of aluminum with copper sulfate should be odorless and have a bright blue color.
Copper plating technology by immersion method
Copper plating of aluminum metal by completely immersing the workpiece in an electrolyte is carried out using the following technology:
- The surface of the workpiece is cleaned with sandpaper or a brush, then degreased in a hot soda solution and washed under running water.
- Two electrodes are suspended into the prepared container and connected to the positive terminal of the power source.
- A workpiece is placed between the electrodes and connected to the negative terminal of the power supply.
- The prepared electrolyte is poured into the working container. The solution level should be above the top edge of the electrodes.
- Using the adjustment device, the operating current value is set. The parameter value is calculated at the rate of 10-15 mA per 1 cm2 of the area of the workpiece being processed.
- After 20 minutes, the power is turned off and the workpiece is removed from the bath.
- The remaining electrolyte is washed off with water and the part is dried.
The process time is indicated approximately; it can be controlled visually by the color of the coating and the uniformity of its distribution. The longer the power is connected, the thicker the aluminum copper plating layer will be.
Work on copper plating of metal workpieces without immersion in the electrolyte is carried out on large products that cannot be completely immersed in the bath. This method is also more effective when processing individual parts of the product.
To perform technological operations for copper plating without immersion in the electrolyte, you will need the following devices:
- The brush for applying the chemical composition is made of stranded copper wire. For this purpose, you need to strip the insulation at one end of the wire, then slightly separate the individual conductors. To make it convenient to hold the brush, it is better to tie it to a wooden stick or pencil.
- It is better to place the workpiece to perform the work in any container without high sides. It is convenient to use an ordinary porcelain or glass plate. Additionally, you will need a container for electrolyte, into which the brush will be constantly dipped. You can use a glass for this purpose.
Source: https://FB.ru/article/456810/mednenie-alyuminiya-v-domashnih-usloviyah-vidyi-i-tehnologii
Use of copper
Due to its numerous advantages, this metal has become widespread. Today, copper and its numerous alloys are widely used in industry.
The metal is relevant for aircraft manufacturing, automotive manufacturing, instrument making and other industries. Metal and products made from it are no less popular in the domestic sphere.
Copper plating itself is one of the best ways to coat a metal surface with a thin layer. At home, copper plating can be done in several ways.
Galvanic copper plating at home
For this you will need:
- Copper sulfate;
- Water;
- Hydrochloric acid in its pure form.
Galvanic copper plating at home
Preparation of the solution
Copper sulfate
We make a saturated solution of copper sulfate, after which you will need to add 1/3 of this solution to hydrochloric acid. After preparing the copper sulfate solution, it should be thoroughly stirred so that there are no particles. Next, you need to add hydrochloric acid in a thin stream to this solution. Don't forget about safety precautions and use gloves and safety glasses. After you have added hydrochloric acid to the solution, it should be mixed thoroughly.
So, the solution is ready and you can start copper plating at home. To do this, you need to take the metal part on which you are going to apply a layer of copper and prepare it for work. Preparation includes sanding it with sandpaper.
This procedure allows you to not only clean the metal surface, but also degrease it. The same procedure will be relevant for parts made of brass or lead. After this, the coating must be thoroughly washed in a solution of soda ash.
This will allow the material to be degreased more thoroughly.
Soda ash for degreasing material
Next, the surface must be immersed in a solution of copper sulfate and hydrochloric acid. Please note that the first layer of copper is very thin and weak, so it is advisable to remove it with a wire brush.
After you have done this, the surface of the steel or lead should be washed again in a solution of soda ash and again immersed in the copper plating solution.
These manipulations will lead to the fact that the layer of copper on the surface at home will be much thicker and much stronger, since it can be removed from the object only using sandpaper, and not a metal brush as before.
This method allows you to make a very high-quality copper coating that can only be removed with sandpaper. To improve the copper coating at home, the part should be immersed in the solution again. This method is distinguished by its simplicity and high efficiency, including for lead products.
Copper plating procedure
Copper plating is usually called the procedure for galvanic deposition of copper; the thickness of the copper layer in such cases can be from 300 microns or more. Copper plating of steel is one of the most important processes in electroplating, as it is used as an additional process before applying other metals for chrome plating, nickel plating, and silver plating.
The copper layer adheres perfectly to the steel and is able to smooth out various defects on the surface.
Copper coatings are characterized by high adhesion to other surfaces, lead products, especially metal ones, as well as high electrical conductivity and ductility. The newly applied coating has a bright pink matte or shiny color. Under the influence of atmospheric influences, copper coatings can oxidize and become covered with a coating of oxides with various rainbow-colored spots.
Areas of use of copper plating
Generally, electroplating copper plating can be used:
- For decorative purposes. Given the enormous popularity of antique copper products these days. There are methods of artificial aging of steel products;
- In galvanoplasty. Widely used in jewelry, among souvenirs, for making bas-reliefs, etc.;
- In the technical industry. Copper plating of metal is very important in the electrical field. The low cost of copper plating compared to gold or silver coatings makes it possible to reduce the cost of manufacturing electrodes, electrical busbars, contacts and other elements from lead steel.
Copper plating occurs together with the application of other galvanic coatings
- If you need to apply a multi-layer protective and decorative coating to a layer of steel. In the vast majority of cases, copper is used here together with nickel and chromium. This allows you to improve adhesion to the base metal and obtain a shiny, high-strength coating;
- To avoid cementation of the area. Copper plating of lead will prevent carbonization from occurring on steel areas. To apply the copper layer, use only those areas where cutting will be carried out;
- When performing restoration and restoration work. This method is most often used to restore chrome parts of cars and motorcycles. For these purposes, a fairly thick layer of copper is applied, about 100-250 microns or more, which makes it possible to cover all defects and damage to the metal for applying subsequent coatings;
Home copper plating
This procedure is relevant for various cases, since applying a layer of copper can be used for aluminum cutlery, souvenirs, candlesticks, etc. Non-metal products on which a layer of copper has been applied have a unique effect. These can be plant stems, leaves, etc. Due to the fact that the objects being coated do not have a conductive layer, a special electrically conductive varnish is used instead, which is applied to the surface.
The varnish contains a number of organic solvents, foaming agents and finely dispersed graphite powder, which creates electrical conductivity.
The varnish is applied in a thin layer to a dry surface, and after drying in an hour, you can begin copper plating. If desired, copper can be given different color shades using special methods.
The high quality and uniqueness of such products is deservedly equated to real jewelry.
: Copper plating at home
Source: https://masakarton.com/kak-pokryt-medyu-stal-v-domashnih-usloviyah/
How to coat metal with copper at home? — Comfort of Your Home
The process of copper plating of metal products is called electroplating. It is based on the deposition of another metal, soluble in a special liquid, onto the surface of parts.
Copper plating technology includes the production of a solution and the creation of dissimilar electrodes. During the electroplating process, copper ions dissolved in the electrolyte are attracted by the negative pole (workpiece) to its surface.
Copper plating of various parts on an industrial scale is used not only as a final process for treating the surface of metal products. It can be used to prepare parts for the next operation, for example, nickel, silver or chrome plating of products.
These metals do not deposit well on the surface of steel parts, but they adhere very well to copper-plated surfaces. In turn, copper deposited on steel parts holds firmly and helps smooth out various defects on its surface.
Copper plating in copper sulfate
The process of copper plating of surfaces of various metals can be carried out not only as the final metalworking procedure, but also as preparation for subsequent finishing.
Technology implemented in industry involves the use of specialized equipment, solutions and skills. But the procedure for coating metal with copper plating can also be carried out at home.
In this article we will look at how to coat metal with copper at home, what is needed for this and what nuances exist.
Process concept
Copper plating is a procedure in which a small layer of copper is applied to the surface of an object. Typically, a galvanic method is used, which involves the transfer of copper ions from a positive to a negative source to the surfaces being treated.
As a rule, copper plating is carried out for the subsequent application of nickel or chromium, but often this procedure becomes an independent technological operation for the final finishing. This is an actively used electroforming process that requires the creation of a copper coating.
In what cases is it used?
There are several situations in which copper plating is required:
- Decoration. Using technology, you can give surfaces a special “aged” look.
- Galvanic copper plating. This method is used in the production of copies of certain copper parts of various shapes and dimensions. It is planned to create wax or plastic bases, which are subsequently coated with electrolytes and copper layers. The technique is actively used in the creation of souvenirs, jewelry products, and decor.
- Electrical engineering. Due to its low cost, the technology stands out favorably against the background of gold or silver plating. Copper-plated elements are used as contacts or electrodes.
The technology can be combined with a variety of galvanizing tasks:
- When creating multi-layer decors with little protection. As a rule, copper is used together with chromium and nickel. This increases the level of adhesion to the base surface.
- In the process of forming protection for certain areas of parts during carburization.
- During restoration. By restoring parts by copper plating, intermediate layers are created, which subsequently serve as the basis for spraying more durable chrome and nickel coatings.
Features of carrying out in domestic conditions
Galvanostegy is the name given to the procedure of copper plating of metal products. Its essence is that the object being processed is immersed in an electrolyte with precipitated copper sulfate. Not everyone knows that galvanization can be done with your own hands at home and does not require special equipment or skills. Thanks to it, you can prepare the surface for the next stage of processing or carry out an intermediate stage before applying chromium, nickel or brass.
Metal after such treatment increases its resistance to aggressive influences.
At home, as a rule, chemical galvanization of minor parts is carried out, because... this will not require serious expenses or additional equipment.
Required materials and equipment
Source: https://morflot.su/omednenie-v-mednom-kuporose/
How to conduct copper plating of metal at home
The process of copper plating of surfaces of various metals can be carried out not only as the final metalworking procedure, but also as preparation for subsequent finishing.
Technology implemented in industry involves the use of specialized equipment, solutions and skills. But the procedure for coating metal with copper plating can also be carried out at home.
In this article we will look at how to coat metal with copper at home, what is needed for this and what nuances exist.
Copper plating of parts at home in two ways - step-by-step instructions with video
When it comes to electroplating, technological operations such as chrome plating and galvanizing of metal products immediately come to mind. But if you ask the question, what is galvanostegy, not everyone will answer - it has been verified. Although this term does not imply anything supernova.
Simply put, this is a technique for coating any material with a thin layer of metal, be it steel, aluminum, wood or plastic. We’ll figure out how to copper-plate a sample at home.
Copper plating and electroplating at home
Surface treatment of various objects is carried out to give a decorative effect or as an intermediate procedure preceding further actions. Many processes are easy to implement and do not require much equipment. One of the most popular processing methods is copper plating, which can also be done at home.
Process Features
The coating formed on the workpiece using galvanization can be applied for technological purposes or perform decorative, protective, or both functions at once. For decorative purposes, a thin layer of gold or silver is created, and to ensure reliable protection of the surface of the workpiece from corrosion, galvanizing or galvanic copper plating is performed.
Electrolysis process diagram
It is not difficult to do electroplating even at home. This procedure is performed as follows.
- Two anodes are lowered into a dielectric container with electrolyte, connected to the positive contact of the electric current source. The material used to manufacture such anodes must be metal, the layer from which must be formed.
- The workpiece itself, connected to the negative terminal of the electric current source and thus acting as a cathode, is placed in the electrolyte between the anodes.
- Galvanization, that is, the process of transferring metal molecules from the electrolyte to the cathode product, begins to occur at the moment when the resulting electrical network is closed.
As a result, a thin and uniform layer of metal is formed on the treated surface, which was originally contained in the chemical composition of the electrolyte.
Galvanic installation diagram
The purpose of copper plating of metals and their scope of application
Copper has a set of properties that determine the conditions for its use in copper plating of metals and non-metallic materials. It is plastic, easy to polish, and the galvanic layer after copper plating has virtually no pores.
For this reason, copper coatings are very often used as a sublayer for chrome and nickel plating of products that are operated under conditions of constant compression and tension. The ductility of copper is an ideal condition for its use in electroforming.
Thick-layer copper plating of artistic products and complex models allows you to create their absolutely exact copies that do not crack or deform when removed from the original.
Copper has the best electrical conductivity among base metals and is easily soldered. Therefore, copper plating of steel products is widely used in radio engineering and electrical engineering in the manufacture of conductors, contacts, antenna parts and waveguides. When high-frequency signals are used, the copper coating experiences a high current density (skin effect), which reduces the overall resistance of the conductor.
Another area of use of copper plating is the creation of thin conductors on the surfaces of plastic products, as well as the coating of plastic with conductive layers.